Funny I am the opposite, I usually prefer my Padron's in maduro, but the 85 I prefer in Natural.85th Maddy. Usually prefer the natural in Padron, but really like this cigar.
My favorite Padron (really hard to choose just one, I'm a Padron whore), is probably the FR45 Maduro. Others that are really good are the 64 Principe maduro, FR85 natural, FR46 maduro, 26#9 maduro, and 64 Diplomatico maduro.